If you want ThrottleStop to start up with Windows 7 or Windows Vista then add it to the Task Scheduler. This example shows me adding RealTemp but you can also use this method to add ThrottleStop to the Task Scheduler.
Open up Task Scheduler and start by clicking on Create Basic Task... on the right hand side.

Enter a name for the task, ThrottleStop, and then click on Next.

For Trigger, choose the option, When I log on.

For Action select, Start a program and then click on Next.

In this example, I dragged the RealTempBeta folder into the Program Files(x86) folder.
Click on Browse and tell it where it can find ThrottleStop.exe

Click Next to go to the Summary window.
Before clicking Finish select, Open the Properties dialog for this task when I click Finish

Now select, Run with highest privileges and click on OK and you're done.

Now reboot and see if it works.
I know this is a big hassle but when running UAC, it's the correct way to add items to your Start Up routine that need Administrator privileges. Temperature monitoring programs need to run at this level to access the temperature sensors which are a protected resource.
If you follow the above method exactly then it should work with or without UAC enabled and whether you are in an Admin or Standard account.

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